Demikian pula dengan Liverpool, sebagai runner-up grup A, Liverpool memiliki pilihan calon lawan terdiri dari Bayern Muenchen, Real Madrid, Porto, dan Benfica.

Calon Lawan Tim-tim yang Lolos Babak 16 Besar:

Napoli:
PSG, RB Leipzig, Borussia Dortmund, Eintracht Frankfurt, Club Brugge

Porto:
Liverpool, PSG, RB Leipzig, Borussia Dortmund, Inter Milan, Eintracht Frankfurt, AC Milan

Bayern Muenchen:
Liverpool, PSG, Club Brugge, AC Milan

Tottenham:
PSG, RB Leipzig, Borussia Dortmund, Inter Milan, Club Brugge, AC Milan

Chelsea:
PSG, RB Leipzig, Borussia Dortmund, Inter Milan, Eintracht Frankfurt, Club Brugge

Real Madrid:
Liverpool, PSG, Borussia Dortmund, Inter Milan, Eintracht Frankfurt, Club Brugge AC Milan

Manchester City:
PSG, RB Leipzig, Inter Milan, Eintracht Frankfurt, Club Brugge, AC Milan

Benfica:
Liverpool, Club Brugge, Inter Milan, Eintracht Frankfurt, AC Milan, RB Leipzig, Borussia Dortmund

Liverpool:
Bayern Munich, Real Madrid, Porto, Benfica

Club Brugge:
Bayern Munich, Manchester City, Real Madrid. Chelsea, Tottenham, Napoli, Benfica

Inter Milan:
Manchester City, Real Madrid, Chelsea, Tottenham, Porto, Benfica

Eintracht Frankfurt:
Manchester City, Real Madrid, Chelsea, Porto, Napoli, Benfica